The Hydrogenation of Benzil Catalyzed by Cobalt(II) Dimethylglyoxime Complex
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چکیده
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متن کاملLow-pressure hydrogenation of carbon dioxide catalyzed by an iron pincer complex exhibiting noble metal activity.
A highly active iron catalyst for the hydrogenation of carbon dioxide and bicarbonates works under remarkably low pressures and achieves activities similar to some of the best noble metal catalysts. A mechanism is proposed involving the direct attack of an iron trans-dihydride on carbon dioxide, followed by ligand exchange and dihydrogen coordination.
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1986
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.59.823